Tubes won't emit an odor from anything inside them - there is no gas exchange (or if there is, the tube does not work). New tubes may off-gas some paint fumes from whatever has been painted on them. Old tubes, when heated, will off-gas whatever has been spilled/deposited on them. So to answer your question, you have to figure out what has been deposited on your tubes; hopefully this has been under your control.
I wouldn't worry too much about hazardous, per-se. But the odor can be a nuisance, and it is best to reduce exposure in any case. I recommend a gentle dusting (turn power OFF first). If you can easily do so, remove the tubes, one at a time, and gently wipe them off before replacing them.
Doesn't hurt to air out the practice pad every now and then, too. I've been to some real stink-holes before. Those places have a bit too much "personality" for me.
- Thom